1. You should order concrete with at least 2000 psi, but go for the 3000 psi if the price is ok. You tell the ready mix company what you are going to use it for and they will know what you need.
2. Make sure you pour the concrete in separate sections. No more than 15'x15'. Even better if you can go with the 10 or 12 feet. This is very important for crack control. You can also pour it in one large section and cut it later, but that takes more experience.
3. Level the ground, wet it and keep moist up till the time you pour. This will keep the concrete from drying.
4. If you plan to drive over it you may want to use steel reinforcement in the form of wire-mesh. Make sure you place it in the middle of the slab and not lying on the ground.
5. You can use a straight 2x4 over the forms to level the concrete. When it starts to dry you can use a trowel to make it smooth, or rough broom to give a non-skid finish.
6. VERY IMPORTANT - start wetting the concrete after 4-5 hours (or sooner if it looks hard and dry) and keep it wet for 3-7 days. The longer the better. You can cover it with wet burlap or plastic to make sure it stays wet.
These are just some of the important points. You should either find someone who has done that before to help you, or go to the library (or book store) and check one of the many books on "Do-it-yourself" projects. You can get good step-by-step instructions for beginners